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Beilstein J. Org. Chem. 2011, 7, 270–277, doi:10.3762/bjoc.7.36
Graphical Abstract
Scheme 1: Photoinduced domino reaction of adamantylphthalimide.
Scheme 2: Synthesis of homoadamantylphthalimide 5.
Figure 1: Molecular structure of 5, the geometry optimization was performed by use of DFT B3LYP/6-31G.
Scheme 3: Products after irradiation of 5.
Scheme 4: Proposed mechanism for the photochemical transformation of 5.